ANALYSIS AND SELECTION OF EFFECTIVE REGENERATION METHODS FOR SORBENTS USED IN GAS PURIFICATION FROM HARMFUL COMPOUNDS
DOI:
https://doi.org/10.66960/jof.3093-8899.00026Keywords:
sorbents, regeneration, gas purification, MDEA, H₂S, CO₂, energy efficiencyAbstract
This paper analyses regeneration methods for sorbents and absorbents used in industrial gas purification from harmful compounds, including H₂S, CO₂, SOx, NOx, volatile organic compounds, and moisture. The relevance of the study is determined by the fact that the efficiency of gas purification units depends not only on the initial sorption capacity of a material but also on the preservation of this capacity during repeated sorption-regeneration cycles. Thermal desorption, steam stripping, vacuum regeneration, chemical washing, reactivation, and electro-/microwave heating are compared. The selection criteria include capacity recovery, specific energy demand, resistance to degradation, corrosion risk, environmental safety, and industrial feasibility. Particular attention is paid to amine gas treating data for the Shurtan Gas Chemical Complex. An increase in CO₂ concentration in feed gas from 2.31 to 3.37 mol.% results in residual CO₂ of 75-100 ppm in treated gas, whereas the design limit is not more than 10 ppm. The analysis shows that replacing 30% DEA with 40% MDEA can reduce steam consumption for regeneration from 64.0 to 52.3 t/h, ensure residual H₂S below 5 ppm and CO₂ below 10 ppm, and improve process stability without replacing the main equipment. The practical significance of the work is the proposed decision-making algorithm for selecting sorbent regeneration methods in gas purification systems of the oil, gas, and gas-chemical industries of Uzbekistan.
References
A. L. Kohl and R. B. Nielsen, Gas Purification, 5th ed. Houston, TX: Gulf Professional Publishing, 1997.
A. J. Kidnay, W. R. Parrish, and D. G. McCartney, Fundamentals of Natural Gas Processing, 3rd ed. Boca Raton, FL: CRC Press, 2019. DOI: https://doi.org/10.1201/9780429464942-1
A. Rojey, C. Jaffret, S. Cornot-Gandolphe, B. Durand, S. Jullian, and M. Valais, Natural Gas: Production, Processing, Transport. Paris, France: Editions Technip, 1997.
D. M. Ruthven, Principles of Adsorption and Adsorption Processes. New York, NY: John Wiley & Sons, 1984.
R. T. Yang, Adsorbents: Fundamentals and Applications. Hoboken, NJ: John Wiley & Sons, 2003, doi: 10.1002/047144409X. DOI: https://doi.org/10.1002/047144409X
G. T. Rochelle, “Amine scrubbing for CO₂ capture,” Science, vol. 325, no. 5948, pp. 1652–1654, 2009, doi: 10.1126/science.1176731. DOI: https://doi.org/10.1126/science.1176731
U. Zahid, “Simulation of an acid gas removal unit using a DGA and MDEA blend instead of a single amine,” Chemical Product and Process Modeling, vol. 15, no. 4, article 20190044, 2020, doi: 10.1515/cppm-2019-0044. DOI: https://doi.org/10.1515/cppm-2019-0044
A. S. Farooqi et al., “Simulation of natural gas treatment for acid gas removal using the ternary blend of MDEA, AEEA, and NMP,” Sustainability, vol. 14, no. 17, article 10815, 2022, doi: 10.3390/su141710815. DOI: https://doi.org/10.3390/su141710815
R. Serna-Guerrero, Y. Belmabkhout, and A. Sayari, “Modeling CO₂ adsorption on amine-functionalized mesoporous silica: 1. A semi-empirical equilibrium model,” Chemical Engineering Journal, vol. 161, no. 1–2, pp. 173–181, 2010, doi: 10.1016/j.cej.2010.04.024. DOI: https://doi.org/10.1016/j.cej.2010.04.024
R. Serna-Guerrero and A. Sayari, “Modeling adsorption of CO₂ on amine-functionalized mesoporous silica: 2. Kinetics and breakthrough curves,” Chemical Engineering Journal, vol. 161, no. 1–2, pp. 182–190, 2010, doi: 10.1016/j.cej.2010.04.042. DOI: https://doi.org/10.1016/j.cej.2010.04.042
R. Desai, M. Hussain, and D. M. Ruthven, “Adsorption of water vapour on activated alumina. I. Equilibrium behaviour,” The Canadian Journal of Chemical Engineering, vol. 70, no. 4, pp. 699–706, 1992, doi: 10.1002/cjce.5450700412. DOI: https://doi.org/10.1002/cjce.5450700412
G. San Miguel, S. D. Lambert, and N. J. D. Graham, “The regeneration of field-spent granular activated carbons,” Water Research, vol. 35, no. 11, pp. 2740–2748, 2001, doi: 10.1016/S0043-1354(00)00549-2. DOI: https://doi.org/10.1016/S0043-1354(00)00549-2
P. D. Sullivan, M. J. Rood, G. Grevillot, J. D. Wander, and K. J. Hay, “Activated carbon fiber cloth electrothermal swing adsorption system,” Environmental Science & Technology, vol. 38, no. 18, pp. 4865–4877, 2004, doi: 10.1021/es0306415. DOI: https://doi.org/10.1021/es0306415
P. L. Llewellyn et al., “High uptakes of CO₂ and CH₄ in mesoporous metal-organic frameworks MIL-100 and MIL-101,” Langmuir, vol. 24, no. 14, pp. 7245–7250, 2008, doi: 10.1021/la800227x. DOI: https://doi.org/10.1021/la800227x
O. Akhmedova and Sh. Akhmedova, “Production of amine absorbents on the basis of local raw materials,” Universum: Technical Sciences, no. 3(120), pp. 53-57, 2024. [Online]. Available: https://7universum.com/ru/tech/archive/item/17124
M. Zh. Makhmudov and S. A. Yomgurov, “Adsorption methods of cleaning and drying gases,” Bulletin of Teachers of the New Uzbekistan, vol. 1, no. 5, pp. 72–75, 2023.
M. J. Makhmudov and R. J. Hamroev, “Research on the effect of the balance, driving force and kinetics of the absorption process on foaming in the process of purification of gases from sour components using MDEA,” Universum: Technical Sciences, no. 11(128), pp. 24-25, 2024. [Online]. Available: https://7universum.com/ru/tech/archive/item/18630
S. A. ugli Joniboev, N. A. Igamkulova, Sh. Sh. Mengliyev, and M. A. Mirzaahmedova, “Physicochemical and chemisorption properties of modified local bentonite sorbents for acid gas removal from expander gas streams,” European Journal of Interdisciplinary Research and Development, vol. 48, pp. 229–235, 2026.
M. Mirzaahmedova and Z. A. Baxodirov, “Gaz-kimyo sanoatida MDEA asosida kislotali gazlarni ajratish texnologiyalarining ilg‘or regeneratsiya usullari,” in Umidli kimyogarlar-2025: XXXIV ilmiy-texnikaviy anjuman maqolalar to‘plami. Toshkent: TKTI, 2025, 57-59 b.
Downloads
Published
Issue
Section
License
Copyright © 2026 Зафар Баходиров, Миржалол Абдубаннобов, Мавлуда Мирзаахмедова, Шерзод Менглиев, Наргиса Игамкулова, Шухраткодир Гуломов

This work is licensed under a Creative Commons Attribution 4.0 International License.
This work is licensed under a Creative Commons Attribution 4.0 International License.

